Catalytic reforming is a chemical process used to convert petroleum refinery, naphthas, typically having low octane ratings, into highoctane liquid products called reformates are components of highoctane gasoline also known as highoctane petrol. Thermal reforming alters the properties of lowgrade. The other links add value to petroleum mainly by moving and storing it e. The applications for stainless steels in petroleum refining are many and varied. Petroleum is a dark brown, thick and viscous liquid which occurs below the earths surface. The oil and gas industry natural resource governance. Petroleum refining petroleum refining naphtha reforming. Catalytic cracking and reforming, thermal cracking, and other secondary processes are used to change the. Petroleum refinery safely, and efficiently transform crude oil and other raw.
Chemistry, refining, fuels and petrochemicals petroleum products james g. A copy of the license is included in the section entitled gnu free documentation license. Petroleum refinery activities start with receipt of. It is a highly endothermic process requiring large amounts of energy. Stock is the harold hitchings burbank professor of political economy in the economics department, harvard university. For it to be the fuel that can go into a car or converted into plastics, it must go through a. The naphtha hydrotreater, which pretreats feed to the reformer. The dominance of monopolies is also a major cause of the corruption that pervades the chinese system. Refineries should establish manual gauging and product receipt procedures to. Steammethane reforming is currently the least expensive way to produce hydrogen, and it accounts for nearly all commercially produced hydrogen in the united states. Speight encyclopedia of life support systems eolss refinery gas c1 c4 161 1 259 31 liquefied petroleum gas c3 c4 42 1 44 31 naphtha c5 c17 36 302 97 575 gasoline c4 c12 1 216 31 421. The use of catalytic naphtha reforming as a process to produce highoctane gasoline continues to be important as it has been over the 55 yr of its commercial use. The other category may also include various small plants using steam reforming, partial oxidation, or autothermal reforming of natural gas, ethane, propane, and liquid hydrocarbon fuels to produce hydrogen.
Basic reactions gasification or partial oxidation is a noncatalytic process. Crude oil is fractionated into liquefied petroleum gas, naphtha used to produce gasoline by blending with octane boosters, keroseneaviation turbine fuel, diesel oil, and residual fuel oil. This training course includes downloadable resources in pdf format with unlimited access. Steam reforming of coke oven gas for hydrogen production. For the purposes of section 3 3 b of the act, if the actual contents of a prescribed vehicle are found to be different in quality or quantity or in any other respect from the particulars of the petroleum delivered to that vehicle as. Permission is granted to copy, distribute andor modify this document under the terms of the gnu free documentation license, version 1. These documents contain everything you need to know about refining process schemes, layouts, crude oil characteristics and properties, petroleum products and much more to download the files. The word petroleum is composed of two latin words petra means rock and oleum means oil. Reforming chinas monopolies strong and may frustrate the desire of the new leadership to push through further reforms to ensure that china avoids the middleincome trap. Page 2 carbon reduction opportunities in the california petroleum industry the five technologies analyzed here do not encompass the full suite of opportunities to reduce greenhouse gas emissions. Most reforming catalysts contain platinum as the active metal supported on alumina, and some may contain additional metals such as rhenium and tin in bi or trimetallic catalyst formulations.
Petroleum is a complex mixture of hydrocarbons and different compounds of sulphur, oxygen and. The engineers guide to plant layout and piping design for the oil and gas industries, 2018. Catalytic naphtha reforming is a major process in the petroleum refinery that. Reforming, in chemistry, processing technique by which the molecular structure of a hydrocarbon is rearranged to alter its properties. Handbook of petroleum processing request pdf researchgate. Petroleum refining and the prod uction of ulsg and ulsd october 24, 2011 page 2 2. Catalytic reforming upgrades straight run naphtha to meet gasoline octane specification and. Over this period, ethanol production and consumption doubled. The steam reforming of coke oven gas cog for hydrogen production was investigated over the niomgo solid solution catalysts reduced at high temperatures. Before describing the reaction chemistry of the catalytic reforming process as used in petroleum refineries, the typical naphthas used as catalytic reforming feedstocks will be discussed. Greenhouse gas emissions from the petroleum refining. Although gasoline can be reformed, it is optimized to meet the demands of ices.
Energy bandwidth for five principal petroleum refining processes. A number of key processes are the major energy consumers in a typical refinery, i. Dear student, welcome to this online course on petroleum refining. Eia expects gasoline production to increase during the summer driving season. Catalytic reforming is a chemical process used to convert petroleum refinery naphthas distilled from crude oil typically having low octane ratings into highoctane liquid products called reformates, which are premium blending stocks for highoctane gasoline. It was found that the niomgo catalyst possessed good catalytic activity, and the conversions of ch4 and co2 were greatly affected by the reaction temperature and steamcarbon sc mole ratio. At the end of each section, you will find downloadable pdf files with everything you need to know about refining process schemes, layouts, crude oil characteristics and properties, petroleum.
Refining what comes out of the ground is not often a form of petroleum that can be used right away. Chapter 8 petroleum for the foreseeable future, oil will remain a critical fuel for the united states and all other industrialized nations. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. Walden oil company in their guide to fluid catalytic cracking reference manual. Onboard reforming of petroleumbased fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. The oil and gas industry overview and trends nrgi reader april 2015 this reader is intended for use in conjunction with the natural resource charter. The most widespread process for rearranging hydrocarbon molecules is naphtha reforming. The purpose of this booklet, therefore, is to help materials engineers identify those applications and to provide data to support the use of stainless steels in the hightemperature, corrosive environments that may be encountered. Hydrogen generation for refineries doe phase ii sbir dr.
The first unit operation in a refinery is the continuous. Nine recommendations methodology for noc case studies our assessment of technicaleconomic performance is a qualitative measure of the degree to which an noc has accomplished the specific goals set out for it by its government principals. Catalytic naphtha reforming is a major process in the petroleum refinery that converts low value naphthas into highoctane reformate product for gasoline blending and into highvalue aromatics for petrochemical processing. Reforming is a process designed to increase the volume of gasoline that can be produced from a barrel of crude oil. Jarullah catalytic reforming catalytic reforming is the process of transforming c7 c10 hydrocarbons with low octane numbers to aromatics and isoparaffins which have high octane numbers. Environmental protection agency research triangle park, north carolina 27711 october 2010. However, the published information on the refinery processes and operation is scant and mostly confined to licensors data, which reveal little beyond what is absolutely necessary for process sale. Commercial hydrogen producers and petroleum refineries use steammethane reforming to separate. Towards better alternatives about the authors abhishek jain is an engineer turned policy researcher, currently working as a junior research associate at the ceew. Petroleum refining begins with the distillation, or fractionation, of crude oils into separate. Reforming is an oil refining operation that produces reformate, a highoctane gasoline blending component. The aspen plus simulation files have been made freely available to the public. Catalytic naphtha reforming is a major process in the petroleum refinery that converts low value naphthas into highoctane reformate product for gasoline.
Combining petroleum coke and natural gas for efficient. This course is designed to provide you with a complete understanding of the crude oil refining industry and breaks down for you all the major refining processes into easily digestible concepts using extensive graphics, process layouts and various manufacturing schemes. Chemistry, refining, fuels and petrochemicals petroleum. Catalytic reforming boosts octane for gasoline blending. Reformate is one of several blending components in finished gasoline. His research focuses on energy access, fossil fuel subsidies, integrated energy planning, circular economy and sustainable development. Refineries, 20172019d 49able 9 t efinery receipts of crude oil by method of r. Petroleum refineries have grown rapidly in complexity and so, too, the refinery operations. Petroleum refining at a glance petroleum refining is a unique and critical link in the petroleum supply chain, from the wellhead to the pump. The process is frequently applied to lowquality gasoline stocks to improve their combustion characteristics. The process converts lowoctane linear hydrocarbons paraffins into branched alkanes isoparaffins and cyclic naphthenes, which are.
Steam reforming of hydrocarbons is the most feasible route today. A petroleum refinery includes many unit operations and unit processes. These are only used as illustrations of the format and content for these key. If co2sequestration is accepted, fossil fuels may play an important role in a starting future. Petroleum refinery process modeling wiley online books. Reforming cracking hydrotreating alkylation coking refining processes involving chemical reactions 29. Request pdf handbook of petroleum processing this extensively updated second. Catalytic reforming in petroleum processing request pdf. The initial process, thermal reforming, was developed in the late 1920s.
Catalytic reforming also provides valuable hydrogen for hydroprocessing units to produce clean fuels. Catalytic reforming is a major conversion process in petroleum refinery and. Catalytic reforming of paraffins to aromatics and hydrogen cannot supply enough h. Catalytic reforming an overview sciencedirect topics. Energy efficiency improvement in the petroleum refining. As a result, 2006 2012 saw a surge in investment in ethanol production capacity, up to the statutory renewable volume obligation rvo of 15 billion gallons bgal of conventional fuels figure 1b.
Available and emerging technologies for reducing greenhouse gas emissions from the petroleum refining industry prepared by the sector policies and programs division office of air quality planning and standards u. Reforming petroleumbased fuels for fuel cell vehicles. The most valuable byproduct from catalytic reforming is hydrogen to satisfy the increasing demand for hydrogen in hydrotreating and hydrocracking processes. This work explores the technical feasibility and economic profitability of converting petroleum coke petcoke and natural gas to liquid. Hydrocarbons in the naphtha stream have roughly the same number of carbon atoms as those in gasoline, but their structure is generally more complex. The text introduces the basics of dealing with the thermodynamics and physical property predictions of hydrocarbon components in. Catalytic reforming in petroleum processing springerlink. Thermal reforming employed temperatures of 510565 c 9501,050 f at moderate pressuresabout 40 bars 4 mpa, or 600 psito obtain gasolines petrols with. Senior economist, health sector, david santley senior petroleum specialist, christopher cantelmi principal.
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